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Gestalt said..Overner said..Gestalt said..
i've been reading a lot of research papers about fillers and the problem is thickening resins within the structural layer weakens the sandwich considerably.
You sure about that? Can you site the papers, please? I would be interested to read them. As I have been reliably given a very different point of view from other people. For example, I did Jury service with a chap who was a professional boat builder and composite specialist who had built composite parts for the Americas Cup Yachts. They used thickened epoxy frequently as part of the sandwich lay up process to reduce the amount of resin take up of HD Foam surfaces. He even described to me how it should be done to get the best weight to strength! If you think about the surface structure of the PVC foam / balsa you will understand why filling them is important, especially if you want a consistent bond.
I would suggest the structural weakness you are alluding to might be to do with resin starvation, rather than the thickened epoxy itself, which means the bond is weaker.
i'm keen to know what you were told.
everything i've found so far points to reduced strength with fillers. makes sense there is less epoxy and less density.
below are some papers i've read. not sure why i can't post links to seabreeze.
Effect of Filler Content on the Performance of Epoxy/PTW Composites (hindawi.com)
Mechanical properties of sandwich composite made of syntactic foam core and GFRP skins (usq.edu.au)
Microsoft Word - 043_Valasek_P (llu.lv)
west systems page also says fillers reduce strength in the section epoxy fillers and epoxy strength.
Epoxy Fillers - modify marine grade WEST SYSTEM Epoxy
I think I understand where you are coming from, with these texts. And with the tests done you would be right. If you put additives in to neat epoxy it will be weaker. To be honest that is sort of a given i.e. put a filler into epoxy and you are increasing the distance between the crosslinked chains.
But... the net benefit of a filler is to bulk out and reduce the density of the resin. The papers you put forwards were testing the strength of the resin itself.
Using a filler to fill the micropores of a high density foam core surface is quite a different application of the filler to what is described in your sited papers. What I am trying to achieve by filling the micro pores is create an homogenous surface for the rest of my laminate to stick to. A bit like putting spackle on a blank. If you imagine the surface as a honeycomb (or in the case of polystyrene lots of gaps between spheres), you can either let the foam absorb resin to fill the spaces - which is heavy, dense and expensive - or you can prefill these holes with a much lower density thickened epoxy. This makes the surface flatter, giving a good surface for your laminate to stick to.
Next time you have some left over resin laminate the surface of some polystyrene and smear resin into the holes. You will find when it is cured there there are lots of resin nests. These nests are denser, tougher, more brittle than the surrounding material. When you pull your laminate off the polystyrene you will bring the resin nest with you and some of the balls of polystyrene. If you had a failure the crease line will be around the denser resin where the low density material meets the high density resin. So the way to get a more consistent surface is to fill the gaps with a material closer in density and material properties to get that flat homogeneous surface. It will also be cheaper and lighter.
The filling of the PVC surface has been advice from several composite builders, with a view to improve the bond between the laminate and the gap filling sandwich component - i.e. the PVC / Balsa / Cork etc. It is not used in the structural resin layer within the laminate itself. Although if you are after some interesting characteristics, it is possibly to use polyurethane additives to epoxy to allow the epoxy more 'give' before complete failure. I have tried this in composite alaias when I wanted the board to be more bendy. It worked better than I had expected, although the surface was a PITA to finish as my normal hot coat just flaked off in sheets.
Does that help?