Way too much of the time (it detracts from sailing), I work in a remote health centre. Chubb turns up annually and checks the fire extinguishers. The bloke pays special attention to all the gas/powder extinguishers - like those usually used in yachts.
He inverts the extinguisher and whacks it with a plastic mallet till the settled/packed powder breaks up and moves, then gives in a few further whacks and shakes to ensure its well and truly loosened up. He reckons this process is even more important for extinguishers used in vehicles and boats, as the fire retardant capacity of the extinguisher is severely diminished if the powder doesn't mix with the gas.
Given the potential issues with fires on boats, I thought this info worth sharing!