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keensailor said..
, am I doing something wrong, should I be cleaning the bare metal with something before priming. Maybe I am using crappy products?
Most cars these days are made with galvanized panels and zinc based primers so using phosphoric acid (will is what a lot of rust converters contain) will only make things worse as the acid reacts with the zinc and turns it into phosphate and hydrogen gas. Once the acid seeps into seams and cracks it will do even more damage as it removes any remaining zinc protection and any zinc based paint to use on top of it so you'll end up with even more rust then if you left it alone . Unless restoring a pre 90s classic forget turning rust into metal potions or acids and instead try to seal the rust using products like Penetrol or POR 15 then paint over that.
The way I'd fix it would be to remove all the crap from previous repair attempts with a wire buff or brush and scraper, sand it lightly if necessary and start again. Run the tip of a Stanley knife tip along the rusty seam to scrape any rust including paint covered rust. Then clean everything with metho a couple of times and use a hairdryer or electric heatgun over the seam to dry moisture trapped between the sheetmetals. Brush a few generous coats of Penetrol on the seam at 5-10 minutes intervals over the course of a few hours so it saturates the rust in between sheets. If is very rusty mix some turps in the first few coats of Penetrol so it goes in even deeper.
After 2-3 hours if you going to spray it with auto 2k primer clean the Penetrol from the surface before it fully cures then next day spray it. If you're just patching it with a paintbrush there is no need to wait, use turps based paint and mix some Penetrol in that, up to 50% in the first coat and no more then 5-10% in the last coat. The Penetrol will remove the paint brush marks and the job will look like it was done with the spray gun.