I am not sure if this will help...But I shall have a go. My explanation is based on (1). The bike has more than one front chain guide, and (2). Multiple chain sprockets at the back.
The front chain guide moves sideway when you pull on the level which possibly be on the handle-bar. The sideway pressure will force the chain off to the sprocket from the current one to the adjacent one. Please note that you don't ever pull the level while the sprocket is not moving. If you did, it will cause damage to the chain guide and also potentially damage the chain.
The back sprockets work in very similar way. It has a spring tensioner which takes up the slack when you go from a larger sprocket to a smaller one. That way, the chain is always tight on whichever sprocket. You mentioned it has 7 speeds. Can I assume that it has 7 sprockets ? If so, there is another thing you need to be aware of. You should never run the bigger/biggest front sprocket with the biggest back sprocket. Why ? Because it will create a lot of friction on the chain as it now has a sharper angle between the front and back. In my experience, I would use the large front with the smaller 3, and the smaller front with the larger 3. I did have 5 sprockets at the back.
Please note that unless you have a set of unusual sprockets, you should not need to worry about the alignments as bikes are very standardised. If the sprockets are way out of alignment, then may be the frame had suffered some traumatic events
How do you test your alignment? Lay the bike on its handle bar and seat. Crank the bike up and shift the gear levels. Check to see if the chain or sprockets are creating abnormal noises. As I said, don't ever muck around with the gear level while the bike is stationary.
I hope that is what you are looking for